Ion-Selective Electrode for cadmium ion (ELIT 8241 crystal membrane)

Reference electrode: double junction lithium acetate (ELIT 003n)

Dual electrode head (ELIT 201)

ELIT Computer Interface/Ion Analyser, or Ion/pH/mV meter.

Standard solution: 1000 ppm Cd as Cd(NO₃)₂

Buffer solution (ISAB): 5 Molar NaNO₃.

150 ml polypropylene beakers, 100ml volumetric flask, 1, 2, 5, 10ml pipettes.

Before use, the electrodes must be calibrated by measuring a series of known standard solutions, made by serial dilution of the 1000ppm standard solution. For a full calibration, prepare 100ml of solutions containing 1000, 100, 10, 1, and 0.1ppm Cd. If the approximate range of concentrations of the samples is known, and this is within the linear range of the ISE, then it is only necessary to make two solutions (preferably a decade apart) which span this range.

NB: If the samples to be measured are expected to have a total ionic strength of greater than 0.001 Molar, or a pH of >7 then 2 ml of buffer solution should be added to each 100ml standard and mixed thoroughly to compensate for different activity coefficients between samples and standards.

Follow the instructions in the General Operating Instructions to measure these standard solutions and prepare a calibration graph.

For samples with low ionic strength and pH < 7, no sample preparation is necessary. Simply take approximately 50 to 100 mls of sample in a plastic beaker, or even immerse the electrodes directly in a lake or river (but take care to avoid losing the electrodes!). For high ionic strength samples (or pH>7), take 100mls of sample and add 2 mls of buffer solution and stir well before measurement.

Follow the instructions in the electrode operating instructions to measure a series of samples and record the results. Briefly, it is important to note that, if measuring in beakers, the electrodes must be washed and dried between each sample, to avoid cross contamination, and sufficient time must be allowed (2 or 3 minutes), before taking a reading after immersion, to permit the electrode signal to reach a stable value. For the highest precision, frequent recalibration is recommended (see operating instructions).

The results will be displayed as ppm and mol/l. If buffer solution has been added equally to standards and samples then these figures will not need adjusting because they will all be affected by the same dilution factor.

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Technical Specifications
for the Cadmium Ion-Selective Electrode (ELIT 8241)

Click here to download a printer-friendly (pdf) Specification Sheet.